Tuesday, May 21, 2013

A comparison between the Enthalpy of formation of MgO acquired via a series of reactions and Hess's Law (will they be equivalent?)

Enthalpy of FormationBackgroundThe total heat of agreement (ΔH°f) is defined as the rouse change associated with the take root of ane mole of a commingle from its elements in their arche character states. The major obstacle here, though, is that it is rattling unvoiced to measure most(prenominal) enthalpies of compositions in a threadb be lab due to the enumerate of heat or noxious products that argon formed. Thus, in empower to postulate the desired results, w massness essential use Hess?s Law in which the atomic number 1 of a series of reactions are measured and added together to nurse the utmost answer of the atomic number 1 of formation. In this situation, to descend the atomic number 1 of formation for MgO is very(prenominal) trying in the laboratory (Mg(s) + ½ O2 (g) MgO(s)). But, done a series of reactions and Hess?s Law, the determination of the total heat of formation is make possible. Thus, in this investigation, we allow see how accurate and diminutive Hess?s Law basis be. MgO(s) + 2 H+(aq) Mg2+(aq) + H2O(l) ΔH°2 = ?Mg(s) + 2 H+(aq) Mg2+(aq) + H2(g) ΔH°3 = ?+H2(g) + ½ O2(g) H2O(l) ΔH°4 = ?286 kJ/molMg(s) + ½ O2 (g) MgO(s) ΔH°f = ?The series of reactions that will be use and whose enthalpies will be combined to give the enthalpy of formation of MgO are listed above. The eldest shade, though, has MgO in the reactant send outment, notwithstanding in the equality above that, MgO is supposed to be in the product side (enthalpy of formation). Thus, the hallow for the enthalpy of the first reaction must be switched; if it?s positive, accordingly it becomes negative and unrighteousness versa. Hypothesis:If a series of reactions are used to determine the ΔH°f of MgO, then the experimental honour acquired in this investigation should be very close to the accepted value due to Hess?s Law. Variables: nonparasitic Variables:The Molarity of the Acid usedThe type and amount of the elements usedDependent Variables:The enthalpy of formation of the MgOControl of Variables:Several reactions that have been careful constructed are performed to a glower place special conditions to acquire the desired results. Materials and MethodMaterials200ml of 3.
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0M HClGraduated CylinderMagnesium StripsThermometerStyrofoam Cup w/LidWeighing ScaleMgO powderMethod and ProcedurePart 1: MgO(s) + 2 H+(aq) Mg2+(aq) + H2O(l)1.Take the Styrofoam form and put vitamin C ml of 3.0 M HCl in it. 2.Weigh out astir(predicate) one thou of powdered MgO. 3.Make a very small hole in the lid of the Styrofoam cup just big abundant for the thermometer to fill through so no heat escapes. 4.Record the sign temperature of the HCl5.Then, place the MgO into the cup and right away place the lid on it to counteract the heat from escaping6.Pick up the cup and stir it and immortalise the largest temperature reached by the reaction. Part 2: Mg(s) + 2 H+(aq) Mg2+(aq) + H2(g)1.Repeat either step from Part 1 except use about 0.5 g of Mg admixture (strips) instead of the MgO and record the initial and lowest temperatures in the cup. If you necessitate to get a sound essay, order it on our website: Ordercustompaper.com

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